Kim, 30, teamed her gown with a pair of forty-carat platinum diamond danglers by Lorraine Schwartz and a matching platinum ring.
The clincher was the drape of fabric in the center, which put the dress and Kardashian in a league of their own.
Other stars shined as they walked the red carpet at the event, many of them reaching the heights of Hollywood glamour. Especially pleasing were Hilary Swank, Amy Adams, and Natalie Portman.
Big winners of the night included Natalie Portman for Best Actress, Colin Firth for Best Actor, and Melissa Leo and Christian Bale for Best Supporting Actress and Actor respectively. The team for The King's Speech won for Best Ensemble Cast.